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Question

Chemistry Question on Electrochemistry

When an electric current is passed through acidified water, 112mL112\, mL of hydrogen gas at N.T.P. was collected at the cathode in 965965 seconds. The current passed, in ampere, is :

A

1

B

0.5

C

0.1

D

2

Answer

1

Explanation

Solution

At cathode: 2H+(aq)+2eH2(g)2 H ^{+}( aq )+2 e^{-} \rightarrow H _{2}( g )

At NTP, 22.4L22.4\, L or 22400mL22400\, mL of H2=1molH _{2}=1\, mol of H2H _{2}
112mL112\, mL of H2=122400×112=0.005molH _{2}=\frac{1}{22400} \times 112=0.005\, mol of H2H _{2}

We know n=I×tFn =\frac{I \times t}{F}
0.005=I×9652×96500I=1A0.005 =\frac{I \times 965}{2 \times 96500} \Rightarrow I=1\, A