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Question

Chemistry Question on Chemical Reactions

When acetone reacts with bleaching powder, the compound formed is:

A

CH3COOHC{{H}_{3}}COOH

B

CH3CHOC{{H}_{3}}CHO

C

CHCl3CHC{{l}_{3}}

D

CCl4CC{{l}_{4}}

Answer

CHCl3CHC{{l}_{3}}

Explanation

Solution

Acetone reacts with bleaching powder to form chloroform. The reaction is in three steps as follows: (i) CaOCl2Bleaching powder+H2OCa(OH)2+Cl2\underset{\begin{smallmatrix} Bleaching \\\ \,\,powder \end{smallmatrix}}{\mathop{CaOC{{l}_{2}}}}\,+{{H}_{2}}O\xrightarrow{{}}Ca{{(OH)}_{2}}+C{{l}_{2}} (ii) CH3COCH3Acetone+3Cl2\underset{Acetone}{\mathop{C{{H}_{3}}COC{{H}_{3}}}}\,+3C{{l}_{2}}\xrightarrow{{}} CCl3COCH3+3HClTrichloroacetone\underset{\text{Trichloroacetone}}{\mathop{CC{{l}_{3}}COC{{H}_{3}}+3HCl}}\,\, (iii)