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Question

Chemistry Question on Amines

When acetamide reacts with NaOHNaOH and Br2Br_2, methyl amine is formed. The reaction occurs through intermediate formation of isocyanate.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Answer

If both assertion and reason are true and reason is the correct explanation of assertion.

Explanation

Solution

CH3CONH2+Br2+4NaOH>CH3NH2+Na2CO3+2NaBr+2H2O {CH3CONH2 + Br2 + 4NaOH -> CH3NH2+ Na2CO3 + 2NaBr + 2H2O} The reaction occurs through intermediate formation of alkyl isocyanate which on hydrolysis gives methylamine and sodium carbonate.