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Question: When a graph between log K and 1/T is drawn a straight line is obtained. The point at which line cut...

When a graph between log K and 1/T is drawn a straight line is obtained. The point at which line cuts y -axis and x -axis respectively correspond to the temp :

A

0, Ea / 2.303 R log A

B

\infty, Ea / (R ln A)

C

0, log A

D

None of these.

Answer

\infty, Ea / (R ln A)

Explanation

Solution

logK=[Ea2.303R]×1T+logAatYaxies[1T]=0T=\log K = \left\lbrack \frac{- E_{a}}{2.303R} \right\rbrack \times \frac{1}{T} + \log AatYaxies\left\lbrack \frac{1}{T} \right\rbrack = 0T = \infty

at×axislogk=0Ea2.303R×1T=logAEaRInA=Tat \times axis \log{}k = 0 \frac{- E_{a}}{2.303R} \times \frac{1}{T} = - \log A \frac{E_{a}}{RInA} = T