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Question

Chemistry Question on Some basic concepts of chemistry

When 800 mL of 0.5 M nitric acid is heated in a beaker, its volume is reduced to half and 11.5 g of nitric acid is evaporated. The molarity of the remaining nitric acid solution is x×102Mx × 10^{–2} M. (Nearest integer)
(Molar mass of nitric acid is 63 g mol–1)

Answer

m moles of HNO3=800×0.5HNO_3=800×0.5
Moles of HNO3=400×103=0.4HNO_3=400×10^{−3}=0.4 moles
Weight of HNO3=0.4×63g=25.2HNO_3 = 0.4 × 63 g= 25.2 g
Remaining acid =25.211.5=13.7= 25.2 – 11.5= 13.7 g
M=13.7×1000400×63M=\frac {13.7×1000}{400×63}

M=137252M=\frac {137}{252}
M=0.54M=0.54
M=54×102M=54×10^{−2}
Given that, The molarity of the remaining nitric acid solution is x×102Mx×10^{−2} M.
On comparing, x=54x= 54

So, the answer is 5454.