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Question: When 100 ml Ca(OH)<sub>2</sub> solution of 0.01 M is diluted with water, the pH of the resulting sol...

When 100 ml Ca(OH)2 solution of 0.01 M is diluted with water, the pH of the resulting solution changes to 12. Volume of water added is –

A

10 ml

B

50 ml

C

100 ml

D

200 ml

Answer

100 ml

Explanation

Solution

Molarity of [OH]Ca(OH)2\lbrack OH^{-}\rbrack_{Ca(OH)_{2}} = 0.02 M (M1)

V1 = 100 ml

V2 = ?

M2 = 10–2 (pH = 12, pOH = 2, [OH] = 10–2)

Ž 0.02 × 100 = V2 × 10–2

Ž V2 = 200 ml

Ž So volume of H2O added = V2 – V1 = 100 mL