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Question

Chemistry Question on coordination compounds

What will be the value of x in Fe++, if the magnetic moment μ=24\mu = \sqrt{24} BM

A

0

B

2

C

1

D

3

Answer

2

Explanation

Solution

The value of x in Fe++ can be determined by considering the magnetic moment (µ) and the number of unpaired electrons in the Fe++ ion.
In an Fe++ ion, the iron atom loses two electrons, resulting in a 2+ charge.
To determine the number of unpaired electrons, we can use the fact that the magnetic moment (µ) is given by the formula:
μ=n(n+2)\mu = \sqrt{n(n+2)} BM Where n represents the number of unpaired electrons.

Given that µ=24µ = \sqrt{24} BM,
we can solve for n: n(n+2)=24\sqrt{n(n+2)} = \sqrt{24}
Squaring both sides: n(n+2)=24n(n+2) = 24
Expanding the equation: n2+2n=24n^2 + 2n = 24
Rearranging and simplifying: n2+2n24=0n^2 + 2n - 24 = 0
Factorizing the quadratic equation: (n4)(n+6)=0(n - 4)(n + 6) = 0
Solving for n: n = 4 or n = -6

Since the number of unpaired electrons cannot be negative, we discard the n = -6 solution.
Therefore, the Fe++ ion has 4 unpaired electrons.
In Fe++, x represents the oxidation state of iron.
Since Fe++ has a 2+ charge, the value of x is 2.
Therefore, the correct value of x in Fe++ is (2) 2.