Question
Question: What will be the resultant \(pH\) when \(200mL\) of an aqueous solution of \(HCl\) \((pH = 2.0)\) is...
What will be the resultant pH when 200mL of an aqueous solution of HCl (pH=2.0) is mixed with 300mL of an aqueous solution of NaOH (pH=12.0).
[Note :write the value to the nearest integer].
Solution
At first think about the pHof an aqueous solution. pH is defined as a scale used to specify the acidity or basicity of an aqueous solution.
Complete step by step answer:
pH is really a measure of the relative amount of free hydrogen and hydroxyl ions in the water. pH is given by −log[H+].
The hydrogen ion concentration of hydrochloric acid of pH=2.0 is 0.01M.
The number of moles of hydrogen ions present are 0.01×0.2=0.0020
The hydrogen ion concentration of sodium hydroxide of pH =12.0 is 0.01M.
The number of moles of hydrogen ions present are 0.01×0.3=0.0030
In 0.0030 moles of hydroxide ions, 0.0020 moles will be neutralized with 0.0020 moles of hydrogen ions.
The remaining hydroxide ion concentration is 0.50.0010=0.0020M
We all know that, pOH=−log[OH−]
The pOH of the solution is pOH=−log0.0020=2.699
The pH of the solution is
pH=14−pOH pH=14−2.699 pH=11.301 pH≈11
The resultant pH of the solution is 11.
Note:
The pH scale is logarithmic and inversely indicates the concentration of hydrogen ions in the solution. Lower pH values correspond to solutions which are more acidic in nature whereas higher values correspond to solutions which are more basic or alkaline.