Solveeit Logo

Question

Question: What will be the resultant \(pH\) when \(200mL\) of an aqueous solution of \(HCl\) \((pH = 2.0)\) is...

What will be the resultant pHpH when 200mL200mL of an aqueous solution of HClHCl (pH=2.0)(pH = 2.0) is mixed with 300mL300mL of an aqueous solution of NaOHNaOH (pH=12.0)(pH = 12.0).
[Note :write the value to the nearest integer].

Explanation

Solution

At first think about the pHpHof an aqueous solution. pHpH is defined as a scale used to specify the acidity or basicity of an aqueous solution.

Complete step by step answer:
pHpH is really a measure of the relative amount of free hydrogen and hydroxyl ions in the water. pHpH is given by log[H+] - \log [{H^ + }].
The hydrogen ion concentration of hydrochloric acid of pH=2.0pH = 2.0 is 0.01M0.01M.
The number of moles of hydrogen ions present are 0.01×0.2=0.00200.01 \times 0.2 = 0.0020
The hydrogen ion concentration of sodium hydroxide of pHpH =12.0 = 12.0 is 0.01M0.01M.
The number of moles of hydrogen ions present are 0.01×0.3=0.00300.01 \times 0.3 = 0.0030
In 0.00300.0030 moles of hydroxide ions, 0.00200.0020 moles will be neutralized with 0.00200.0020 moles of hydrogen ions.
The remaining hydroxide ion concentration is 0.00100.5=0.0020M\dfrac{{0.0010}}{{0.5}} = 0.0020M
We all know that, pOH=log[OH]pOH = - \log [O{H^ - }]
The pOHpOH of the solution is pOH=log0.0020=2.699pOH = - \log 0.0020 = 2.699
The pHpH of the solution is
pH=14pOH pH=142.699 pH=11.301 pH11  pH = 14 - pOH \\\ pH = 14 - 2.699 \\\ pH = 11.301 \\\ pH \approx 11 \\\
The resultant pHpH of the solution is 1111.

Note:
The pHpH scale is logarithmic and inversely indicates the concentration of hydrogen ions in the solution. Lower pHpH values correspond to solutions which are more acidic in nature whereas higher values correspond to solutions which are more basic or alkaline.