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Question

Chemistry Question on States of matter

What will be the relation between the T1T_1 of gas 11 with M1=56M_1 = 56 and T2T_2 of gas 22 with M2=44M_2 = 44 if the average speed of gas 11 is equal to most probable speed of gas 22 ?

A

T1=T22T_1 =T^2_2

B

T1=T2T_1 = T_2

C

T1=(T2)1/2T_{1}=\left(T_{2}\right)^{1/2}

D

T1=1/T2T_{1}=1/T_{2}

Answer

T1=T2T_1 = T_2

Explanation

Solution

cav=8RTπM;c_{av}=\sqrt{\frac{8RT}{\pi M}} ;
cmp=2RTMc_{mp}=\sqrt{\frac{2RT}{M}}
Given that, 8RT1πM1=2RT2M2\sqrt{\frac{8RT_{1}}{\pi M_{1}}}=\sqrt{\frac{2RT_{2}}{M_{2}}}
8T1πM1=2T2M2\Rightarrow \frac{8T_{1}}{\pi M_{1}}=\frac{2T_{2}}{M_{2}}
4T1π×56=T244\frac{4T_{1}}{\pi\times56}=\frac{T_{2}}{44}
T1T2=56×π44×4=1\Rightarrow \frac{T_{1}}{T_{2}}=\frac{56\times\pi}{44\times4}=1
T1=T2\Rightarrow T_{1}=T_{2}