Question
Question: What will be the pressure of the gaseous mixture when \(0.5L\) of \({H_2}\) at \(0.8bar\) and \(2.0L...
What will be the pressure of the gaseous mixture when 0.5L of H2 at 0.8bar and 2.0L of dioxygen at 0.7bar are introduced in a 1L vessel at 27∘C ?
Solution
The ideal gas law states that the product of the pressure and the volume of one gram molecule of an ideal gas is equal to the product of the absolute temperature of the gas and the universal gas constant. Ideal gas is a gas whose particles exhibit no attractive interactions whatsoever; at high temperatures and low pressures, gases behave close to ideally.
Formula used:
PV=nRT
P= Pressure
V= Volume
n= Amount of substance
R= Ideal gas constant
T= Temperature
Complete answer:
Given:
P1=0.8bar
V1=0.5L
P2=0.7bar
V2=2.0L
To find: Pressure of gaseous mixture of H2 and O2
For H2 gas,
Substituting the given values in the ideal gas formula,
P1V1=n1RT
0.8×0.5=nH2×0.0821×300
nH2=0.016
For O2 gas
Similarly, for O2 , Substituting the given values in the ideal gas formula,
P2V2=n2RT
0.7×2=nO20.0821×300
nO2=0.056
For mixture
PV=nRT
P×1=(nH2+nO2)×0.0821×300
P=(0.016+0.056)×0.0821×300
P=1.79bar
Hence, the pressure of the gaseous mixture is 1.79bar .
Note:
When the particles of a gas are so far apart that they do not exert any attractive forces on one another, the gas is said to be ideal. There is no such thing as an ideal gas in real life, but at high temperatures and low pressures (conditions in which individual particles move very swiftly and are very far apart from one another, with essentially no interaction), gases behave very similarly to ideally.