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Question

Chemistry Question on The solid state

What type of crystal defect is indicated in the diagram below ? Na+ClNa+ClNa+Cl { Na^{+} Cl^{-} Na^{+} Cl^{-} Na^{+} Cl^{-}} ClClNa+Na+ {Cl^{-} \Box \, Cl^{-} Na^{+} \Box Na^{+}} Na+ClClNa+Cl {Na^{+} Cl^{-} \Box Cl^{-} Na^{+} Cl^{-}} ClNa+ClNa+Na+ {Cl^{-} Na^{+} Cl^{-} Na^{+} \Box Na^{+}}

A

Interstitial defect

B

Schottky defect

C

Frenkel defect

D

Frenkel & Schottky defects

Answer

Schottky defect

Explanation

Solution

Schottky defect is a defect which is produced when one cation and anion are missing from their respective positions leaving behind a pair of holes. The crystal as a whole remains neutral because the number of missing positive ions (cations) and negative ions (anions) is the same.