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Question: What mass of metal is present in a 45.8g mass of barium sulphate?...

What mass of metal is present in a 45.8g mass of barium sulphate?

Explanation

Solution

This problem can be easily solved by using the formula to find the no. of moles. Once the no. of moles of Barium are known, the mass of barium (in grams) can be found out by multiplying the moles of barium with the molar mass of barium metal.

Complete answer:
The formula for Barium Sulphate can be given as BaSO4BaS{O_4} .
To find the no. of moles present in 45.8 g of BaSO4BaS{O_4} we need to find the molar mass of BaSO4BaS{O_4} .
The molar mass of BaSO4BaS{O_4} = molar mass of Ba + molar mass of S + 4×4 \times molar mass of oxygen.
The molar mass of Barium =137g/mol = 137g/mol
Molar mass of Sulphur =32g/mol = 32g/mol
Molar mass of Oxygen =16g/mol = 16g/mol
The molar mass of Barium Sulphate =137+32+4×16=233g/mol = 137 + 32 + 4 \times 16 = 233g/mol
The no. of moles of a substance can be given by the formula: Moles=mass(g)MolarMass (g/mol)Moles = \dfrac{{mass(g)}}{{MolarMass{\text{ }}(g/mol)}}
No. of moles of BaSO4BaS{O_4} in 45.8 g =45.8233=0.0196mol = \dfrac{{45.8}}{{233}} = 0.0196mol
Barium sulphate has one mole of barium, one mole of sulphur and 4 moles of oxygen. We are concerned with only the barium atom. Therefore, the no. of moles of Barium Metal in BaSO4BaS{O_4} is 0.0196 moles.
The mass (in grams) of Barium in 0.0196 moles =moles×Molar MassBarium=0.0196×137 = moles \times Molar{\text{ }}Mas{s_{Barium}} = 0.0196 \times 137
Mass of barium present in 45.8 grams 27g \cong 27g
This is the required answer.

Note:
Barium Sulphate is the sulphate salt of barium. Barium sulphate has two components; one is the barium and second is the sulphate anion. The central atom sulphur is attached to four oxygen atoms. The colour of BaSO4BaS{O_4} is crystalline white. It is insoluble in water and also in alcohol. It is soluble in acids and has no odour.