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Question: What is the VSEPR model for \( C{O_2} \) ?...

What is the VSEPR model for CO2C{O_2} ?

Explanation

Solution

The arrangement of atoms in simple and symmetric molecules are determined by VSEPR theory. The central metal atom and terminal atoms arrangement and bonded electrons, lone pairs geometry can be explained by this theory. Based on the central metal atom and lone pairs, bonded electrons carbon dioxide is AX2A{X_2} system.

Complete answer:
Carbon dioxide is the molecule consisting of carbon and two oxygen atoms. The valence electrons of carbon are 44 and the valence electrons of the oxygen atom is 66 and the two oxygen atoms have 1212 electrons. The total valence electrons of carbon dioxide are 1616 electrons. Out of these 1616 electrons, eight electrons are bonded pairs of electrons and the remaining eight electrons are existing as lone pairs of electrons on oxygen atoms due to the electronegativity of oxygen.
VSEPR theory stands for valence shell electron pair repulsion. According to this theory, bonding and non-bonding electrons of the central metal atom in a molecule will repel each other and give the molecular shape.
Some notations were given by this theory to explain the geometry of the molecule:
AX2A{X_2} linear
AX3A{X_3} trigonal planar
AX3EA{X_3}E trigonal pyramidal
AX2E2A{X_2}{E_2} bent
AX4A{X_4} tetrahedral
Carbon dioxide has AX2A{X_2} notation, as A is the central metal atom which is carbon and X is the terminal atom which is oxygen.
Thus, according to VSEPR theory, CO2C{O_2} is linear.

Note:
The lone pair of electrons on the central metal atom is also responsible for the prediction of geometry of molecules. In the molecule of carbon dioxide, there were two lone pairs of electrons on each oxygen atom, but not lone pairs on central metal atom carbon. Thus, it belongs to AX2A{X_2} notation.