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Question

Chemistry Question on Bond Parameters

What is the total number of sigma and pi bonds in the following molecules?

  1. C2H2C_2H_2
  2. C2H4C_2H_4
Answer

a. A single bond is a result of the axial overlap of bonding orbitals. Hence, it contributes a sigma bond. A multiple bond (double or triple bond) is always formed as a result of the sidewise overlap of orbitals. A pibondpi-bond is always present in it. A triple bond is a combination of two pibondspi-bonds and one sigma  bondsigma \;bond.
Structure of C2H2C_2H_2 can be represented as:
Structure of C2H2
Hence, there are three sigma and two pibondspi-bonds in C2H2C_2H_2.


The structure of C2H4C_2H_4 can be represented as:
The structure of C2H4
Hence, there are five sigma bonds and one pibondpi-bond in C2H4C_2H_4.