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Question

Chemistry Question on Equilibrium

What is the pH of the resulting solution when equal volumes of 0.1MNaOH0.1\, M \,NaOH and 0.01M0.01\, M HClHCl are mixed ?

A

7

B

1.04

C

12.65

D

2

Answer

12.65

Explanation

Solution

N1V1N2V2=N.V.{N_1V_1 - N_2V_2 = N.V.}
0.1×10.01×1=N×2{0.1 \times 1 - 0.01 \times 1 = N \times 2 }
[OH]=NR=0.092=0.045  N{[OH^{-}] = N_R = \frac{0.09}{2} = 0.045 \; N }
pOH = - log (0.045) = 1.35
\therefore pH = 14 - pOH = 14 - 1.35 = 12.65