Question
Question: What is the pH of a \(0.500M\) solution of acetyl salicylic acid, \[pK = 3.52\]?...
What is the pH of a 0.500M solution of acetyl salicylic acid, pK=3.52?
Solution
We know that Dissociation constant Ka is a quantitative proportion of the strength of an acid in solution. It is the balance steady for a substance response. It is otherwise called as
Otherwise called acidity constant or acid ionization constant.
The equation f an acid constant is as follows,
Ka=[HA][A−][H+]
The pKa value can be calculated using the equation,
pKa=log[A−][H+][HA]
Complete answer:
We have to remember that the pKa esteem is one technique used to show the strength of an acid. pKa is the negative log of the acid separation steady or ka esteem. Lower pKa esteem shows a more grounded acid. That is, the lower esteem demonstrates the acid all the more completely separates in water.
The relationship between ph and pKa is,
pH=[AH]pKa+log10[A−]
In case of weak acid pH can be calculated as,
pH=21(pKa−loga)
Here a is the concentration of an acid.
It is given that the pK value is 3.52.
The concentration of acid is 0.5M.
pH=21(3.52−log(0.5))
pH=21(3.52−(−0.301))
On simplification we get,
pH=1.91
The pH of the solution is 1.91.
Note:
We need to remember that the pH is defined as the quantitative proportion of the basicity and acidity of fluid. The term, broadly utilized in science, science, and agronomy, deciphers the upsides of the grouping of the hydrogen particle—which conventionally goes between around 1 and 10−14 gram-reciprocals per liter—into numbers somewhere in the range of 0 and 14. In unadulterated water, which is impartial (neither acidic nor antacid), the convergence of the hydrogen particle is 10−7 gram-reciprocals per liter, which relates to a pH of 7 .Solution with a pH under 7 is considered acidic; Solution with a pH more prominent than 7 is viewed as fundamental, or basic.