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Question

Chemistry Question on Unit Cells

What is the percentage of free space in body centered cubic unit cell?

A

0.32

B

0.2

C

0.34

D

0.28

Answer

0.32

Explanation

Solution

For bcc unit cell,
Packing fraction = Total volume of spheres  Volume of the unit cell =\frac{\text { Total volume of spheres }}{\text { Volume of the unit cell }}
=83πr36433r3=0.68=\frac{\frac{8}{3} \pi r^{3}}{\frac{64}{3 \sqrt{3}} r^{3}}=0.68.
%\therefore \% of occupied space
=0.68×100=0.68 \times 100
=68=68
%\therefore \% of free space =10068=32=100-68=32