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Question: What is the oxidation state of Mn in \( \text{KMn}{{\text{O}}_{4}} \) ? (A) \( -7 \) (B) \( -3 ...

What is the oxidation state of Mn in KMnO4\text{KMn}{{\text{O}}_{4}} ?
(A) 7-7
(B) 3-3
(C) 0
(D) +3+3
(E) +7+7

Explanation

Solution

M0M++e{{\text{M}}^{0}}\to {{\text{M}}^{+}}+{{\text{e}}^{-}} oxidation reaction +1+1
M++eM0{{\text{M}}^{+}}+{{e}^{-}}\to {{\text{M}}^{0}} Reduction 0
Oxidation state is the hypothetical charge an atom would have if all bonds to atoms of different elements were treated as ionic.

Complete step by step Solution
KMnO4\text{KMn}{{\text{O}}_{4}} dissociated as K+{{\text{K}}^{+}} and MnO4\text{MnO}_{4}^{-} .
Thus we will now calculate the oxidation number of Mn l. let us suppose it has an oxidation state of X. Thus the equation is –
1+X8=01+\text{X}-8=0
Thus the value of X is +7+7
The equation has been written in that manner because KMnO4\text{KMn}{{\text{O}}_{4}} has an overall oxidation number of 0.K has an oxidation number of +1+1 and o has an oxidation number on both the sides should be balanced and hence we get the value to be +7+7
So option E correct answer

Additional information
The oxidation number of a free element is always 0.
The oxidation number of a monatomic ion equals the charge of the ion.
The oxidation number of H is +1+1 , but it is 1-1 in when combined with less electronegative elements.
The oxidation number of O in compounds is usually 2-2 , but it is 1-1 in peroxides.
Rules of Assigning Oxidation Number to Elements
Rule 1: the oxidation number of an element in its free state is zero
Rule 2: the oxidation number of monatomic ions is the same as the charge on the ion.
Rule 3: the sum of all oxidation numbers in a neutral compound is zero.

Note
Oxidation number also called oxidation state, the total number of electrons that an atom either gains or loses in order to form a chemical bond with another atom.The oxidation number of hydrogen is almost always +1+1 when it is in a compound.