Question
Question: What is the oxidation state of Mn in \( \text{KMn}{{\text{O}}_{4}} \) ? (A) \( -7 \) (B) \( -3 ...
What is the oxidation state of Mn in KMnO4 ?
(A) −7
(B) −3
(C) 0
(D) +3
(E) +7
Solution
M0→M++e− oxidation reaction +1
M++e−→M0 Reduction 0
Oxidation state is the hypothetical charge an atom would have if all bonds to atoms of different elements were treated as ionic.
Complete step by step Solution
KMnO4 dissociated as K+ and MnO4− .
Thus we will now calculate the oxidation number of Mn l. let us suppose it has an oxidation state of X. Thus the equation is –
1+X−8=0
Thus the value of X is +7
The equation has been written in that manner because KMnO4 has an overall oxidation number of 0.K has an oxidation number of +1 and o has an oxidation number on both the sides should be balanced and hence we get the value to be +7
So option E correct answer
Additional information
The oxidation number of a free element is always 0.
The oxidation number of a monatomic ion equals the charge of the ion.
The oxidation number of H is +1 , but it is −1 in when combined with less electronegative elements.
The oxidation number of O in compounds is usually −2 , but it is −1 in peroxides.
Rules of Assigning Oxidation Number to Elements
Rule 1: the oxidation number of an element in its free state is zero
Rule 2: the oxidation number of monatomic ions is the same as the charge on the ion.
Rule 3: the sum of all oxidation numbers in a neutral compound is zero.
Note
Oxidation number also called oxidation state, the total number of electrons that an atom either gains or loses in order to form a chemical bond with another atom.The oxidation number of hydrogen is almost always +1 when it is in a compound.