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Question

Question: What is the oxidation number of \( N \) in \( NH_4^+ \) ?...

What is the oxidation number of NN in NH4+NH_4^+ ?

Explanation

Solution

To solve the given question, we should have knowledge about oxidation numbers and how to calculate it. Oxidation Number is the number of electrons gained or lost or shared to form a compound from an element.

Complete step by step answer:
Some general rules that follow oxidation number are that the oxidation number of a free element is always 00, the oxidation number of a Group 11 element in a compound is +1+1 , a Group 22 element in a compound is +2+2 and the sum of oxidation numbers of all of the atoms in a compound is of the total charge of the molecule.
Step-1 :
The Nitrogen atom has different oxidation numbers with different atoms to form a different number of compounds. Oxidation state of Nitrogen generally is 3-3.
Step-2 :
If we look at any other compound like nitrate which has a formula of NO3NO_3^- . The oxidation state of nitrogen can be calculated as the Oxidation number of N+3×N+3 \times Oxidation number of oxygen = Total charge on the molecule.
x+3(2)=1x+3(-2)=-1
x=+5x=+5
Step-3 :
Now, if we look forward to the given compound as a whole is not neutral, in fact, it contains a charge of a positive one. So, the oxidation number of nitrogen here can be calculated as :
x+4=+1x+4=+1
x=3x=-3

Note:
The nitrogen gas has a molecular formula of which is neutral, so, the charge is zero in this case. The atomic number of Nitrogen is 77 with a mass of 14amu14amu .
While calculating the oxidation number of an atom in a compound, make sure to determine the charge of the whole compound as it is the most important step while calculating the oxidation number.