Question
Question: What is the name of the compound that has the formula \( PC{l_3} \) ?...
What is the name of the compound that has the formula PCl3 ?
Solution
The given formula PCl3 indicates that this compound is an example of phosphorus trihalides. Also the covalency of phosphorus in trihalides is 3 . By looking at the formula, we can think that phosphorus is attached to three chlorine atoms.
Complete answer:
We all know that phosphorus forms two halides i.e. phosphorus trihalide (PX3) and phosphorus pentahalide (PX5) . The covalency of phosphorus in phosphorus trihalide (PX3) is 3 and the covalency of phosphorus in phosphorus pentahalide (PX5) is 5 .
The given formula PCl3 indicates that this compound is an example of phosphorus trihalides. The name of the compound with formula PCl3 is Phosphorus trichloride. It is one of the common examples of phosphorus trihalide. The hybridization of phosphorus in PCl3 is sp3 . It has a pyramidal structure. In phosphorus trichloride structure PCl3 , three sp3 hybrids orbitals of phosphorus overlap with the p- orbitals of the chlorine and form three P−Cl sigma bonds and the fourth sp3 hybrid orbital contains lone pairs of electrons.
Additional Information:
Phosphorus trichloride acts as a nucleophile due to the presence of lone pairs of electrons and it also acts as an electrophile due to the presence of empty d-orbital. Phosphorus trichloride generally undergo redox reactions.
Note:
Phosphorus trichloride is a very reactive compound. It is very poisonous and volatile in nature. It is present in a colourless oily liquid state. It has a very pungent odour. It shows an explosion when it reacts with water. It is highly toxic in nature and causes irritation to eyes, skin and respiratory system. It is a very important reagent which is widely used in organic chemistry.