Question
Question: What is the name of \(Co{{F}_{2}}\)?...
What is the name of CoF2?
Solution
The "international union of pure and applied chemistry" governs the nomenclature of organic and inorganic chemical compounds. The name of a compound should be systematic and be able to depict and determine the unambiguous formula of a chemical compound.
Complete answer:
Some rules for naming simple inorganic chemical compound are
- Compounds with a single negative charge or anions have the suffix -ide.
For example, H− is hydride.
- The name of the cation or the compound with a positive charge is usually simply the name of the element and followed by the name of the anion.
For example, CaCl2 is calcium chloride.
- Compounds having more than a single positive charge, or cations are labeled using roman numbers after the name of the cation in brackets.
For example, Mn+ is manganese(I) and Mn2+ is manganese(II), etc.
- Polyatomic anions containing oxygen or oxyanions have suffix -ite for a lesser quantity of oxygen and suffix -ate for the greater quantity of oxygen.
For example, the anion NO3− is written as nitrate, and the anion NO2− is written as nitrite.
In presence of 4 oxyanions, the prefix hypo- is used for a single oxygen atom, and the prefix per- is used for 4 oxygen atoms.
For example, the anion ClO− is written as hypochlorite, and the anion ClO4− is written as perchlorate.
- The presence of hydrogen is depicted by either the name hydrogen or the prefix bi-.
For example, the compound NaHCO3 can be called either sodium hydrogen carbonate or sodium bicarbonate.
Now, CoF2 contains +2 positively charged cobalt cation Co+2 and two singly negatively charged fluoride ions F−.
So the name of the compound will be cobalt(II) fluoride.
Note:
It should be noted that ions can be polyatomic. Cations (which are usually metals and positively polyatomic ions) are named before anions (which are usually non-metals and negative polyatomic ions).
Also, some of the prefixes and suffixes indicating oxidation numbers according to the older system are
Oxidation state | Cations and acids | Anions |
---|---|---|
Lowest | -ous, hypo- | -ite, hypo- |
-ous | -ite | |
-ic | -ate | |
-ic, per- | -ate, per- | |
Highest | -ic, hyper- | -ate, hyper-. |