Solveeit Logo

Question

Question: What is the hybrid state of the central atom in the following \(P{F_5},\,C{O_2},\,B{F_4}^ - \) ....

What is the hybrid state of the central atom in the following PF5,CO2,BF4P{F_5},\,C{O_2},\,B{F_4}^ - .

Explanation

Solution

Hybridisation is that concept of chemistry in which we study the mixing of atomic orbitals in order to form a new hybrid orbital with variation in energy, shape, from the parent orbital’s. These new orbits are suitable for the pairing of electrons in order to form new bonds so that a molecule can be made.

Complete answer:
In the first step we count the total valence electrons (T.V.E) of the given central metal atom in the molecule.
Then to calculate the numbers of sigma bonds, divide the T.V.E by 88 .
In case after the division of T.V.E by 88 the remainder is left, divide it by 22 for the calculation of lone pairs.
Now calculate the Steric number by adding the lone pair value and the sigma bond value.
In the case of PF5P{F_5}

The number of sigma bonds is 55 thus the hybridization of the central metal is sp3ds{p^3}d .
In the case of CO2C{O_2}

The hybridization of the central metal is spsp .
In the case of BF4B{F_4}^ -

The hybridization of the central metal is sp3s{p^3} .

Note:
The Steric number calculated for the calculation of the hybridization of the central metal atom in the above case follows the chronology which is as follows: - Iff the Steric number is 22 then the hybridization is spsp . Iff the Steric number is 33 then the hybridization is sp2s{p^2} . Iff the Steric number is 44 then the hybridization is sp3s{p^3} . Iff the Steric number is 55 then the hybridization is sp3ds{p^3}d . Iff the Steric number is 66 then the hybridization is sp3d2s{p^3}{d^2} . . Iff the Steric number is 77 then the hybridization is sp3d3s{p^3}{d^3} .