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Question

Question: What is the equivalent mass of \(IO_{4}^{-}\) when it is converted into \(I_{2}\) in acid medium....

What is the equivalent mass of IO4IO_{4}^{-} when it is converted into I2I_{2} in acid medium.

A

M/6

B

M/7

C

M/5

D

M/4 (e) None of these

Answer

M/7

Explanation

Solution

Equivalent mass

=Molecular weightChange in oxidation number per mole= \frac{\text{Molecular weight}}{\text{Change in oxidation number per mole}}

Suppose molecular weight is MM

Oxidation number of I2I_{2} in IO4IO_{4}^{-} in

Acidic medium i.e., I×(8)+1e=+7I \times ( - 8) + 1e^{-} = + 7

So eq. wt. =M/7= M/7.