Question
Question: What is the equivalent mass of \(IO_{4}^{-}\) when it is converted into \(I_{2}\) in acid medium....
What is the equivalent mass of IO4− when it is converted into I2 in acid medium.
A
M/6
B
M/7
C
M/5
D
M/4 (e) None of these
Answer
M/7
Explanation
Solution
Equivalent mass
=Change in oxidation number per moleMolecular weight
Suppose molecular weight is M
Oxidation number of I2 in IO4− in
Acidic medium i.e., I×(−8)+1e−=+7
So eq. wt. =M/7.