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Question: What is the empirical formula of the compound containing \(36.5\% \) sulfur and \(63.5\% \) Iron? ...

What is the empirical formula of the compound containing 36.5%36.5\% sulfur and 63.5%63.5\% Iron?
A. FeSFeS
B. Fe63S36F{e_{63}}{S_{36}}
C. Fe2SF{e_2}S
D.Fe2S2F{e_2}{S_2}
E. 2FeS2FeS

Explanation

Solution

The empirical formula, often known as the simplest formula, yields the lowest whole number ratio of atoms in a molecule. This formula specifies the relative number of atoms in each element in the compound. Unlike molecular formulas, empirical formulas do not provide information about the absolute number of atoms in a single molecule of a compound.

Complete answer:
100g100g of compound will contain 36.5g36.5g of sulfur (SS ) and 63.5g63.5g of iron (FeFe )
The atomic mass of sulfur is 32.1gmol132.1gmo{l^{ - 1}}
The atomic mass of iron is 55.8gmol155.8gmo{l^{ - 1}}
Number of moles can be calculated by using the following formula:
Number of moles =MassMolar mass\text{Number of moles } = \dfrac{\text{Mass}}{\text{Molar mass}}
Number of moles of SS =36.532.1 = \dfrac{{36.5}}{{32.1}}
Number of moles of SS =1.137 = 1.137
Number of moles of FeFe =63.555.8 = \dfrac{{63.5}}{{55.8}}
Number of moles of Fe=1.137Fe = 1.137
From the above calculations, we can conclude that the ratio of the number of moles of FeFe to the number of moles of SS is 1.137:1.1371.137:1.137 that is 1:11:1 .
Therefore, the empirical formula FeSFeS .
Hence, the correct answer is “Option A”.

Note:
The most basic kind of notation is empirical formulas. A compound's molecular formula is the same as or a whole-number multiple of its empirical formula. Empirical formulas, like molecular formulas, are not unique and can describe a variety of chemical structures or isomers.