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Question: What is the diameter of the largest sphere that will fit in the void at the centre of the cube edge ...

What is the diameter of the largest sphere that will fit in the void at the centre of the cube edge of a BCC crystal of edge length a ?

A

0.134 a

B

0.76 A

C

0.05548 a

D

0.098 a

Answer

0.134 a

Explanation

Solution

x = a24+a24=a22=a2\sqrt{\frac{a^{2}}{4} + \frac{a^{2}}{4}} = \sqrt{\frac{a^{2}}{2}} = \frac{a}{\sqrt{2}}

The atom present in the void will touch the atom at the corner at first

\ rx + r = a/2 ; 4r = 3\sqrt{3}a or r = 3a4\frac{\sqrt{3}a}{4}

\ rx = a2\frac{a}{2}3a4\frac{\sqrt{3}a}{4} = 2a4\frac{2a}{4}3a4\frac{\sqrt{3}a}{4} = a4\frac{a}{4} (2–3\sqrt{3})

= 0.067 a

\ 2rx = 2 × 0.067a = 0.134 a.