Question
Question: What is the conjugate base of \(HN{O_2}\)?...
What is the conjugate base of HNO2?
Solution
The term 'conjugate base' is usually used in conjunction with the term 'conjugate acid' in the chemical world, and it comes from the Brønsted-Lowry theory of Acids and Bases.
The Brønsted-Acid is a proton donor, while the Brønsted-Base is a proton acceptor. These definitions mean that a chemical reaction is needed to distinguish between the 'donor' and 'acceptor' substances. The root of the application can be traced back to the ' Brønsted -Lowry' principle of acids and bases.
Complete step by step answer:
By extracting a proton (H+)from any Brønsted-Lowry acid, the conjugate base can be identified (every Brønsted-Lowry acid has a conjugate base, and vice versa).
Let's look at the chemical reaction where nitrous acid reacts with water:
HNO2(aq)+H2O(l)⇌NO2−(aq)+H3O+(aq)
Here, to form NO2− and the hydronium ion, H3O+ the Brønsted-Lowry acid HNO2, has donated a proton to H2O. This is the forward reaction and in the reverse reaction, NO2− is now the Brønsted-Lowry base (conjugate of HNO2) because it accepts a proton from hydronium (conjugate acid of H2O) to form nitrous acid again.
So, the conjugate base of HNO2 is NO2−
Note:
In an aqueous solution, a monoprotic acid donates either one proton or hydrogen atom per molecule. Monoprotic acids include HNO2, also known as nitrous acid, is a weak acid that only occurs in the form of nitrite salts in solution (NO2−). Remember that the presence of one hydrogen distinguishes a Conjugate Base from an Acid of the Conjugate Base. That is, adding one hydrogen to any anion produces the conjugate base's acid.
Generally:
Anion−+H+⇒H−Anion
Anion−⇒Conjugate Base of the acid H−Anion