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Question: What is the conjugate base of \(HN{O_2}\)?...

What is the conjugate base of HNO2HN{O_2}?

Explanation

Solution

The term 'conjugate base' is usually used in conjunction with the term 'conjugate acid' in the chemical world, and it comes from the Brønsted-Lowry theory of Acids and Bases.
The Brønsted-Acid is a proton donor, while the Brønsted-Base is a proton acceptor. These definitions mean that a chemical reaction is needed to distinguish between the 'donor' and 'acceptor' substances. The root of the application can be traced back to the ' Brønsted -Lowry' principle of acids and bases.

Complete step by step answer:
By extracting a proton (H+)\left( {{H^ + }} \right)from any Brønsted-Lowry acid, the conjugate base can be identified (every Brønsted-Lowry acid has a conjugate base, and vice versa).
Let's look at the chemical reaction where nitrous acid reacts with water:
HNO2(aq)+H2O(l)NO2(aq)+H3O+(aq)HN{O_2}\left( {aq} \right) + {H_2}O\left( l \right) \rightleftharpoons NO_2^ - \left( {aq} \right) + {H_3}{O^ + }\left( {aq} \right)
Here, to form NO2NO_2^ - and the hydronium ion, H3O+{H_3}{O^ + } the Brønsted-Lowry acid HNO2HN{O_2}, has donated a proton to H2O{H_2}O. This is the forward reaction and in the reverse reaction, NO2NO_2^ - is now the Brønsted-Lowry base (conjugate of HNO2HN{O_2}) because it accepts a proton from hydronium (conjugate acid of H2O{H_2}O) to form nitrous acid again.
So, the conjugate base of HNO2HN{O_2} is NO2NO_2^ -

Note:
In an aqueous solution, a monoprotic acid donates either one proton or hydrogen atom per molecule. Monoprotic acids include HNO2HN{O_2}, also known as nitrous acid, is a weak acid that only occurs in the form of nitrite salts in solution (NO2)\left( {NO_2^ - } \right). Remember that the presence of one hydrogen distinguishes a Conjugate Base from an Acid of the Conjugate Base. That is, adding one hydrogen to any anion produces the conjugate base's acid.
Generally:
Anion+H+HAnionAnio{n^ - } + {H^ + } \Rightarrow H - Anion
AnionAnio{n^ - } \Rightarrow Conjugate Base of the acid HAnionH - Anion