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Question

Question: What is the color of anhydrous copper sulphate?...

What is the color of anhydrous copper sulphate?

Explanation

Solution

First we need to know what it means by the term anhydrous. When a crystalline substance loses water, the compound is said to be an anhydrous compound. A crystalline substance can lose its water molecule by various methods like heating, freeze-drying, vacuum, desiccators, etc. to form an anhydrous compound.

Complete answer:
Now, crystalline copper sulfate has the formula CuSO4.5H2OCuS{{O}_{4}}.5{{H}_{2}}O.
Or we can say that when a copper derivative like cupric oxide (CuO), cupric hydroxide (Cu(OH)2Cu{{(OH)}_{2}}), or cupric carbonate (CuCO3CuC{{O}_{3}}) is added to dilute hydro sulfuric acid (H2SO4{{H}_{2}}S{{O}_{4}}), the copper is hydrated to form a blue vitriol or hydrated copper (II) sulfate (CuSO4.5H2OCuS{{O}_{4}}.5{{H}_{2}}O).
This blue vitriol formed is a pentahydrate and has a molar mass of 249.685 g/mol. It is soluble in water and is non-combustible.
Now, when this hydrated copper (II) sulfate (CuSO4.5H2OCuS{{O}_{4}}.5{{H}_{2}}O) or blue vitriol is heated at high temperatures, it loses its water of crystallization (5H2O5{{H}_{2}}O) and forms amorphous copper sulfate (CuSO4CuS{{O}_{4}}).
The blue vitriol turns white upon heating.
Hence, the color of amorphous copper sulfate (CuSO4CuS{{O}_{4}}) is white.
Amorphous copper sulfate (CuSO4CuS{{O}_{4}}) has a powdery texture and has a molar mass of 159.60 g/mol. It decomposes at a temperature of 383 K.

Note:
It should be noted that when water is added to the white amorphous copper sulfate (CuSO4CuS{{O}_{4}}), it regains its water of crystallization to form hydrated copper (II) sulfate (CuSO4.5H2OCuS{{O}_{4}}.5{{H}_{2}}O) or blue vitriol.