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Question

Question: What is the bond angle of \(Si{O_2}{\text{ ?}}\)...

What is the bond angle of SiO2 ?Si{O_2}{\text{ ?}}

Explanation

Solution

Bond angle may be defined as the angle formed between the two covalent bonds originating from the same atom. According to valence shell electron pair repulsion theory we can predict the geometry of the molecule. Bond angle can also be predicted using the geometry of the molecule.

Complete answer:
Silicon Dioxide is formed by combining one silicon atom and two oxygen atoms. Silicon has atomic number 11. Therefore its electronic configuration can be written as 2,8,42,8,4. Thus it has four valence electrons. Therefore it will form four bonds with oxygen. Therefore it can be depict as:

Here there are only two sigma bonds present. Hence it will be spsp hybridized. Therefore we know that the bond angle for spsp hybridized molecule is 180{180^ \circ }.
But in actual silicon dioxide is not a single molecule. Silicon Dioxide exists in a lattice structure where silicon forms four sigma bonds with four oxygen atoms. This lattice structure is the polymer structure of the silicon dioxide. Hence the lattice structure can be depicted as:

Therefore every silicon atom is connected to four oxygen atoms by a sigma bond. Thus here the hybridization of each silicon atom is 109.5{109.5^ \circ }.

Note:
The given lattice structure of silicon dioxide is a snap of the whole structure. The given structure is polymerized to produce the whole structure. The valency of each atom silicon and oxygen is satisfied in the lattice structure. This is the stable structure of silicon dioxide. The molecule which has 109.5{109.5^ \circ } has tetrahedral geometry according to VSEPR. Also there is a lone pair of an electron present on the oxygen atom which may also distort its geometry.