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Question: What is the amount of chlorine evolved when 2 amperes of current is passed for 30 minutes in an aque...

What is the amount of chlorine evolved when 2 amperes of current is passed for 30 minutes in an aqueous solution of O2O_{2}.

A

66 g

B

1.32 g

C

33 g

D

99 g

Answer

1.32 g

Explanation

Solution

At Andoe AtAnodeCl12Cl2+eAtAnodeCl^{-} \rightarrow \frac{1}{2}Cl_{2} + e^{-}

ECl2=35.5×22=35.5E_{Cl_{2}} = \frac{35.5 \times 2}{2} = 35.5

WCl2=ECl2×I×t96500=35.5×2×30×6096500=1.32gmW_{Cl_{2}} = \frac{E_{Cl_{2}} \times I \times t}{96500} = \frac{35.5 \times 2 \times 30 \times 60}{96500} = 1.32gm.