Question
Question: What is the action of following on but- \(2\) -ene? (A)Dil. Alkaline \(KMn{O_4}\) (B) Acidic \(...
What is the action of following on but- 2 -ene?
(A)Dil. Alkaline KMnO4
(B) Acidic KMnO4
Solution
KMnO4 is an inorganic catalyst. The name of this catalyst is Potassium permanganate. KMnO4 has 2 ions K+ and MnO4− ions. The IUPAC name of KMnO4 catalyst is Potassium manganate (VII) . It is widely used in various chemical industries in several laboratories. It KMnO4 is used in a reaction, and then it mostly acts as the oxidizing agent.
Complete answer:
For the first time potassium permanganate was synthesized by, Johann Rudolf Glauber in 1659, when he reacted manganese dioxide with potassium carbonate. The conformation of the reaction was done by a change in color. Initially, the color changes to violet and then to red. The synthesis reaction of the potassium permanganate is as follows:-
2MnO2+4KOH+O2→2K2MnO4+2H2O
2K2MnO4+2H2O→2KMnO4+2KOH+H2
For all MnO2 is manganese dioxide, KOH is potassium hydroxide, K2MnO4 is potassium manganate and KMnO4 is potassium permanganate.
But- 2 -one is an organic compound having formulas as C4H8 . It exhibits the geometrical isomerism that means it exists in cis as well as in trans form. Having molar mass equal to 56.106g/mol . With melting point equals to −138.9∘C and boiling point equals 0.8 to 3.7∘C
(A)In the presence of Dil. Alkaline KMnO4 the product formed is di-alcohol. In the case of but- 2 -ene, Butane- 2,3 - diol is synthesized.
(B)In the presence of acidic KMnO4 the product formed is a carboxylic acid. In the case of but- 2 -ene, Ethanoic acid is synthesized. Before the final product, a ring intermediate is made which leads to all differences in the use of the different types of potassium permanganate.
Note:
It is to remember that two different catalysts will never produce the same products. As the catalysts are different, so the product would be. A catalyst would never itself undergo any short of changes; it only provides an alternative path for the reaction to take place.