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Question

Chemistry Question on Electrochemistry

What is standard reduction potential of Cu2+ | Cu(s) if E° of following cell is 0.46V ? Cu(s) | Cu2+(aqs) || Ag+(aq) | Ag(s) ( Eo = 0.80V)

A

1.56 V

B

1.44 V

C

1.26 V

D

0.34 V

Answer

0.34 V

Explanation

Solution

The overall cell potential, E°cell, is the difference between the reduction and oxidation potentials:
E°cell = E°reduction - E°oxidation
Given E°cell = 0.46V, and E°reduction = 0.80V,
we can rearrange the equation to solve for E°oxidation:
E°oxidation = E°reduction - E°cell
E°oxidation = 0.80V - 0.46V = 0.34V
Therefore, the standard reduction potential of Cu²⁺ | Cu(s) is 0.34V. The correct option is: (D) 0.34 V