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Question: What is \(sp\) hybridization?...

What is spsp hybridization?

Explanation

Solution

Hybridization can be defined as the concept of mixing two atomic orbitals with the same energy levels to give a degenerated new type of orbitals. This intermixing of the atomic orbitals is based on quantum mechanics.

Complete answer:
The redistribution of the energy of the orbitals of individual atoms to give orbitals of equivalent energy takes place when two atomic orbitals combine to form hybrid orbital in a molecule is known as hybridization. The new orbitals formed in this process are known as hybrid orbitals. Based on the types of orbitals involved in mixing, the hybridization can be classified into different types. spsp hybridization is observed when one ss and one pp orbital in the same main shell of an atom mix to form two new equivalent orbitals. The new orbitals formed are known as spsp hybridized orbitals. spsp hybridization is also known as diagonal hybridization. Each spsp hybridized orbital has an equal amount of ss and pp character i.e. 50%50\% ss and pp character. Examples of spsp hybridization: All compounds of beryllium like BeF2,BeH2,BeCl2Be{F_2},Be{H_2},BeC{l_2} and all compounds of carbon containing triple bond like C2H2{C_2}{H_2} . Note that the spsp orbitals are oriented at 180{180^ \circ } to each other.

Note:
The chemical bonding in chemical compounds such as alkynes with triple bonds can be explained by spsp hybridization. The chemical bonding in ethyne consists of spspsp - sp overlap between the two carbon atoms forming a sigma bond and two additional pi bonds formed by ppp - p overlap. Each carbon atom also bonds to the hydrogen atom in a σ ssp\sigma {\text{ }}s - sp overlap at 180{180^ \circ } angles. Hybridization helps us to explain the shape of molecules.