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Question

Chemistry Question on The solid state

What fraction of one edge centred octahedral void lies in one unit cell of fcc?

A

13\frac 13

B

14\frac 14

C

112\frac {1}{12}

D

12\frac 12

Answer

14\frac 14

Explanation

Solution

In a face-centered cubic unit cell, each edge is shared by 4 adjacent unit cells. Therefore, if you consider the edge-centered octahedral void, only 14th\frac 14^{th} of the void is contained within one unit cell. This is because each unit cell contributes 14th\frac 14^{th} of the void, and when you sum up the contributions from all adjacent cells, you get the complete void.

So, the correct option is (B): 14\frac 14