Question
Question: What do you understand about the reactivity series of metals? Write the name of one metal of each wh...
What do you understand about the reactivity series of metals? Write the name of one metal of each which is more reactive and less reactive than hydrogen.
Solution
The reactivity of metals can be defined by the stability of ions, as more the stability ion is more will be the reactivity. Reactivity series is the representation of metals according to their reduction potential or oxidation potential.
Complete step-by-step answer: Reactivity of metal decrease with increase reduction potential therefore metals with more negative reduction potential will displace other metals with less negative reduction potential from their salt solution.
Those metals which have negative reduction potential can liberate hydrogen gas from acid and water except with HNO3 which oxidise H2 gas to H2O and itself reduce to NO2 exceptionally only Mn and Mg can liberate H2 gas from dilute or very dilute HNO3.
Reactivity series or activity series according to increasing reduction potential as we move downward-
Li+/Li Al+3/Al Zn+2/Zn Fe+2/Fe Sn+2/Sn Pb+2/Pb H+/H2 Cu+2/Cu Sn+4/Sn+2 Fe+3/Fe+2 Ag+/Ag
On moving down the group reactivity of metals decreases and reduction potential increases. Down the group oxidising nature increases. The elements on the top can be easily corrode and can react with cold water.
Reduction potential for hydrogen is zero and for metals above hydrogen is negative and for metals below hydrogen is positive. It shows that lithium has a maximum tendency to oxidise and silver has a maximum tendency to reduce.
Lithium is more reactive than hydrogen. While silver is less reactive than hydrogen. Hydrogen is taken as standard for the calculation of reduction potential as it has zero reduction potential, so we can calculate reduction potential of different elements with respect to hydrogen.
Note: Zn,Sn,Fe with HNO3 exceptionally form N2O while other metals with HNO3 produce NO2.
All reactions in which elements with less reduction potential undergo oxidation and other elements with high reduction potential undergo reduction, are always spontaneous.