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Question: What are the quantum numbers of the five electrons of Boron?...

What are the quantum numbers of the five electrons of Boron?

Explanation

Solution

\bullet Boron, B, has an atomic number of 5. This implies that around a neutral Boron atom there will be 5 electrons surrounding its nucleus.
\bullet Electronic configuration of Boron is: 1s22s22p11{{s}^{2}}2{{s}^{2}}2{{p}^{1}}

Complete answer: \bullet Quantum numbers are basically a set of numbers which are used to describe the position and energy of the electron in an atom.
\bullet As we have 5 electrons here that means we will have 5 sets of quantum numbers.

NumberSymbolPossible values
Principle Quantum numbernn1,2,3,.....1,2,3,.....
Angular momentum Quantum numberii0,1,2,.....,(n1)0,1,2,.....,(n-1)
Magnetic Quantum numberml{{m}_{l}}l,....,1,0,1,....,l-l,....,-1,0,1,....,l
Spin Quantum numberms{{m}_{s}}+12,12+\dfrac{1}{2},-\dfrac{1}{2}

\bullet Here, the Electronic configuration of Boron is: 1s22s22p11{{s}^{2}}2{{s}^{2}}2{{p}^{1}} so,
\bullet The 1st{{1}^{st}} electron from the orbital which is highest in energy will come. Because of which, this electron will come from a 2p2p -orbital.
\bullet Principal Quantum number, nn, gives the energy level and here it is equal to 22.
\bullet Angular Momentum Quantum number, ll, gives the subshell in which electrons can be found. Here the electron is located in 2nd{{2}^{nd}} energy level so,
\bullet l=0l=0\to the 2s2s -subshell
\bullet l=1l=1\to the 2p2p -subshell
\bullet Magnetic Quantum Number, ml{{m}_{l}}, gives the actual orbital in which the electrons can be found. There are three possible orbitals for p-subshells
\bullet ml=1{{m}_{{{l}_{{}}}}}=-1\to the px{{p}_{x}}orbital
\bullet ml=0{{m}_{l}}=0\to the py{{p}_{y}} orbital
\bullet ml=+1{{m}_{l}}=+1\to the pz{{p}_{z}} orbital
\bullet Spin Quantum Number, ms{{m}_{s}}, gives the spin of electrons
\bullet ms=+12{{m}_{s}}=+\dfrac{1}{2} \to Spin-up
\bullet ms=12{{m}_{s}}=-\dfrac{1}{2}\to Spin-down
\bullet So, the quantum numbers for the First electron:
First Electron: n=2n=2, l=1l=1, ml=1{{m}_{l}}=-1, ms=+12{{m}_{s}}=+\dfrac{1}{2}
\bullet The Second and Third electrons will come in 2s2s orbital so they will have:
Second Electron: n=2n=2, l=0l=0, ml=0{{m}_{l}}=0, ms12{{m}_{s}}-\dfrac{1}{2}
Third Electron: n=2n=2, l=0l=0, ml=0{{m}_{l}}=0, ms=+12{{m}_{s}}=+\dfrac{1}{2}
\bullet The Fourth and Fifth electron will come in 1p1p orbital so they will have:
Fourth Electron: n=1n=1,l=0l=0, ml=0{{m}_{l}}=0, ms12{{m}_{s}}-\dfrac{1}{2}
Fifth Electron: n=1n=1, l=0l=0, ml=0{{m}_{l}}=0, ms=+12{{m}_{s}}=+\dfrac{1}{2}

Note:
It is really interesting to note that only three quantum numbers are required to specify an orbital while four quantum numbers are required to specify an electron. So, for orbital, three and for electrons, we need four quantum numbers.