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Question: What are \[f\]-block elements \[?\] Distinguish between lanthanoid and actinoid?...

What are ff-block elements ?? Distinguish between lanthanoid and actinoid?

Explanation

Solution

First we know that the elements in the periodic table are arranged into four blocks associated with the four sublevels s,p,d,s,p,d, and ff. This periodic table consists of groups and periods. Lanthanoid and actinoid are ff-block elements in the periodic table.

Complete answer:
ff-block elements are placed separately at the bottom of the periodic table and they are a subset of 6th{6^{th}} and 7th{7^{th}} periods. ff-block elements are the elements in the periodic table in which last electrons enters into ff orbitals or simply, the elements whose ff orbital getting filled up by electrons are called ff-block elements. These block elements also called as inner transition elements because they provide a transition in the 6th{6^{th}} and 7th{7^{th}} row of the periodic table which separates the ss block and the dd block elements.
Difference between lanthanoid and actinoid

LanthanoidActinoid
Lanthanoids are non-radioactive except promethiumActinides are radioactive elements.
Lanthanoid include the elements with atomic numbers starting from 5757 and ending at 7171Actinoids include elements with atomic numbers starting from 8989 and ending at 103103.
Lanthanoids have a low tendency to form complexes.Actinoids have a greater tendency to form complexes.
In lanthanoid, the last electrons enter into 4f4f orbitals.In actinoid, the last electrons enter into 5f5f orbitals.
Binding energy of 4f4f orbital is higher.Binding energy of 5f5f orbital is lower.

Note:
ff-block elements are divided into two series corresponding to the filling up of 4f4f and 5f5f orbitals. The elements from CeCe to LuLu are 4f4f orbital series and ThTh to LrLr are 5f5f orbital series. In each series there are 1414 elements. The first series of elements are called lanthanides and the second series of elements are called actinides.