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Question

Chemistry Question on Some basic concepts of chemistry

Volume of CO2CO_2 obtained by the complete decomposition of 9.85 gm BaCO39.85\ gm \ BaCO_3 is:

A

2.24 lit.2.24 \ lit.

B

1.12 lit.1.12\ lit.

C

0.84 lit.0.84\ lit.

D

0.56 lit.0.56\ lit.

Answer

1.12 lit.1.12\ lit.

Explanation

Solution

Molar mass of Ba = 137.33 g/mol

Molar mass of C = 12.01 g/mol

Molar mass of O = 16.00 g/mol

Molar mass of BaCO3 = 137.33 + 12.01 + 3 x 16.00 = 197.34 g/mol

Moles of BaCO3 = MassMolar mass\frac {Mass }{Molar \ mass }

Moles of BaCO3 = 9.85 g197.34 g/mol\frac {9.85\ g }{ 197.34\ g/mol} ≈ 0.05 moles

Balanced chemical equation for the decomposition of BaCO3

BaCO3BaO+CO2BaCO_3 → BaO + CO_2

The stoichiometry tells us that one mole of BaCO3 produces one mole of CO2.

Moles of CO2 = Moles of BaCO3 ≈ 0.05 moles

Now, use the ideal gas law to find the volume of CO2 at standard temperature and pressure (STP):

The molar volume of an ideal gas at STP is 22.4 liters/mol.

Volume of CO2 = Moles of CO2 x Molar volume at STP

Volume of CO2 = 0.05 moles x 22.4 liters/mole = 1.12 liters

So, the correct option is (B): 1.12 lit.1.12\ lit.