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Question: Using the data given below find out the strongest reducing agent. \[Eº_{CrO_{7}^{2 -}/Cr^{3 +}} = 1...

Using the data given below find out the strongest reducing agent.

EºCrO72/Cr3+=1.33V;EºCl2/Cl=1.36VEº_{CrO_{7}^{2 -}/Cr^{3 +}} = 1.33V;Eº_{Cl_{2}/Cl} = 1.36V

EºMnO4/Mn2+=1.51V;EºCr3+/Cr=0.74VEº_{MnO_{4}^{-}/Mn^{2 +}} = 1.51V;Eº_{Cr^{3 +}/Cr} = - 0.74V

A

ClCl^{-}

B

Cr

C

Cr3+Cr^{3 +}

D

Mn2+Mn^{2 +}

Answer

Cr

Explanation

Solution

Lower the value of reduction potential stronger is the reducing agent i.e., undergoes oxidation most easily.

CrCr3++3eCr \rightarrow Cr^{3 +} + 3e^{-} (oxidation)

Hence, Cr is the strongest reducing agent.