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Question

Chemistry Question on p -Block Elements

Urea reacts with water to form AA which will decompose to form BB. BB when passed through Cu2+(aq)Cu^{2+}(aq), deep blue colour solution C is formed. What is the formula of C from the following

A

CuSO4CuSO_4

B

[Cu(NH3)4]2+[Cu(NH_3)_4]^{2+}

C

Cu(OH)2Cu(OH)_2

D

CuCO3.Cu(OH)2CuCO_3.Cu(OH)_2

Answer

[Cu(NH3)4]2+[Cu(NH_3)_4]^{2+}

Explanation

Solution

NH2CONH2+H2ONH_{2}CONH_{2}+H_{2}O \to
(NH4)2CO3(A)<=>2NH3(B)+H2O+CO2\underset{(A)}{(NH_{4})_{2}CO_{3}} {<=>} \underset{(B)}{2NH_{3}}+H_{2}O+CO_{2}
4NH3(B)+Cu(aq)2+[Cu(NH3)4](aq)2+(deep blue (C)\underset{(B)}{4NH_{3}}+\overset{2+}{Cu(aq)} \to \underset{\text{(deep blue (C)}}{\left[Cu\left(NH_{3}\right)_{4}\right]_{\left(aq\right)}^{2+}}