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Question

Chemistry Question on Thermodynamics

Under isothermal conditions a gas expands from 0.2 dm3 to 0.8 dm3 against a constant pressure of 2 bar at 300 K. Find the work done by the gas.(1 dm3 bar = 100 J)

A

160 J

B

–120 J

C

–40 J

D

20 J

Answer

–120 J

Explanation

Solution

The work done by a gas during expansion or compression:
Work = - PΔV
Here,
ΔV = final volume - initial volume
ΔV = 0.8 dm³ - 0.2 dm³
ΔV = 0.6 dm³
The pressure (P) is given as 2 bar, which we can convert to the corresponding units of dm³ bar:
1 dm³ bar = 100 J
So, 2 bar = 200 J.
Substituting the values into the formula, we get:
Work = - PΔV
Work = -(200 J) x (0.6 dm³)
Work = -120 J
Therefore, the work done by the gas is -120 J, which matches option (B) in the given choices.