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Question

Physics Question on kinetic theory

Two vessels separately contain two ideal gases AA and BB at the same temperature, the pressure of AA being twice that of BB. Under such conditions, the density of AA is found to be 1.5times1.5\, times the density of BB. The ratio of molecular weight of AA and BB is :

A

12\frac{1}{2}

B

23\frac{2}{3}

C

34\frac{3}{4}

D

2

Answer

34\frac{3}{4}

Explanation

Solution

ρA=1.5ρB{{\rho }_{A}}=1.5{{\rho }_{B}}
ρA=2ρB{{\rho }_{A}}=2{{\rho }_{B}}

According to ideal gas equation, we have Pressure,p=ρRTMp=\frac{\rho RT}{M}
, where M is molecular weight of ideal gas.
Such that, pρ=RTMM=ρRTp\frac{p}{\rho }=\frac{RT}{M}\Rightarrow M=\frac{\rho RT}{p}
where, R and T are constant.
So, MρpM\propto \frac{\rho }{p}
MAMB=ρAρB×pBpA=1.5×12=0.75=34\Rightarrow \,\,\frac{{{M}_{A}}}{{{M}_{B}}}=\frac{{{\rho }_{A}}}{{{\rho }_{B}}}\times \frac{{{p}_{B}}}{{{p}_{A}}}=1.5\times \frac{1}{2}=0.75=\frac{3}{4}