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Question

Chemistry Question on States of matter

Two vessels of volumes 16.4L16.4\, L and 5L5\,L contain two ideal gases of molecular existence at the respective temperature of 27?C27^?C and 227?C227^?C and exert 1.51.5 and 4.14.1 atmospheres respectively. The ratio of the number of molecules of the former to that of the latter is

A

22

B

11

C

12\frac{1}{2}

D

13\frac{1}{3}

Answer

22

Explanation

Solution

From p1V1n1T1=p2V2n2T2\frac{p_{1} V_{1}}{n_{1} T_{1}}=\frac{p_{2} V_{2}}{n_{2} T_{2}}
n1n2=p1V1T2p2V2=1.5×16.4×5004.1×5×300=2\frac{n_{1}}{n_{2}}=\frac{p_{1} V_{1} T_{2}}{p_{2} V_{2}}=\frac{1.5 \times 16.4 \times 500}{4.1 \times 5 \times 300}=2
n1:n2=2:1\therefore\, n_{1}: n_{2}=2: 1