Question
Chemistry Question on internal energy
Two rigid boxes containing different ideal gases are placed on a table. Box A contains one mole of nitrogen at temperature T0, while box B contains one mole of helium at temperature (7/3)T0. The boxes are then put into thermal contact with each other, and heat flows between them until the gases reach a common final temperature (Ignore the heat capacity of boxes). Then, the final temperature of the gases, Tf, in terms of/T0 is :
Tf=73T0
Tf=37T0
Tf=23T0
Tf=25T0
Tf=23T0
Solution
Here, change in internal energy of the system is ??cro. i.e., increase in internal energy of one is equal to decrease in internal energy of other. ΔUA=1×25R(Tf−T0) ΔUB=1×23R(Tf−37T0) Now ΔUA+ΔUB=0 25R(Tf−T0)+23R(Tf−37T0)=0 5Tf−5T0+3Tf−7T0=0 ⇒8Tf=12T0⇒Tf=812T0=23T0