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Question

Chemistry Question on internal energy

Two rigid boxes containing different ideal gases are placed on a table. Box AA contains one mole of nitrogen at temperature T0T_0, while box BB contains one mole of helium at temperature (7/3)T0(7/3)\, T_0. The boxes are then put into thermal contact with each other, and heat flows between them until the gases reach a common final temperature (Ignore the heat capacity of boxes). Then, the final temperature of the gases, TfT_f, in terms of/T0T_0 is :

A

Tf=37T0T_{f} =\frac{3}{7}T_{0}

B

Tf=73T0T_{f} =\frac{7}{3}T_{0}

C

Tf=32T0T_{f} =\frac{3}{2}T_{0}

D

Tf=52T0T_{f} =\frac{5}{2}T_{0}

Answer

Tf=32T0T_{f} =\frac{3}{2}T_{0}

Explanation

Solution

Here, change in internal energy of the system is ??cro. i.e., increase in internal energy of one is equal to decrease in internal energy of other. ΔUA=1×5R2(TfT0)\Delta U_{A}=1\times\frac{5R}{2}\left(T_{f} -T_{0}\right) ΔUB=1×3R2(Tf73T0)\Delta U_{B}=1\times\frac{3R}{2}\left(T_{f} -\frac{7}{3}T_{0}\right) Now ΔUA+ΔUB=0\Delta U_{A}+\Delta U_{B}=0 5R2(TfT0)+3R2(Tf7T03)=0\frac{5R}{2}\left(T_{f} -T_{0}\right)+\frac{3R}{2}\left(T_{f} -\frac{7T_{0}}{3}\right)=0 5Tf5T0+3Tf7T0=05T_{f} -5T_{0}+3T_{f} -7T_{0}=0 8Tf=12T0Tf=128T0=32T0\Rightarrow 8T_{f} =12T_{0} \Rightarrow T_{f} =\frac{12}{8}T_{0}=\frac{3}{2}T_{0}