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Question: Two reactions A ¾® products and B ¾® products have rate constant, k<sub>a</sub> and k<sub>b</sub> re...

Two reactions A ¾® products and B ¾® products have rate constant, ka and kb respectively at temperature T and activation energies are Ea and Eb respectively.

If ka> kb and Ea<Eb and assuming the frequency factor A in both the reactions are same then

A

On increasing temperature ka will be greater than kb

B

At lower temperature ka and kb will differ more

C

As temperature rises ka and kb will be close to each other

in magnitude

D

All of the above are correct

Answer

All of the above are correct

Explanation

Solution

ln ka = A – Ea/RT ; ln kb = A – Eb/RT

As temperature rises E/RT become negligible