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Question

Chemistry Question on Unit Cells

Two ions A+A^+ and BB^- have radii 104 and 200 pm respectively, in a cubic close packed crystal of compound AB. The co-ordination no. of A is

A

4

B

8

C

6

D

3

Answer

6

Explanation

Solution

Radius ratio= r+r=104pm200pm=0.52\frac{r_+}{r_-} = \frac{104 \, pm}{200 \, pm} = 0.52 As it lies in the range 0.414 - 0.732, the coordination number will be 6