Question
Chemistry Question on Gas laws
Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300 K. The piston of A is free to move, while that of B is held fixed. The same amount of heat is given to the gas in each cylinder. If the rise in temperature of the gas in A is 30 K, then the rise in temperature of the gas in B is
A
30 K
B
18 K
C
50 K
D
42 K
Answer
42 K
Explanation
Solution
A is free to move, therefore, heat will be supplied at constant
pressure
∴dQA=nCpdtA ...(i)
B is held fixed, therefore, heat will be supplied at constant
volume.
∴dQB=nCvdTB ...(ii)
But dQA=dQB (given)
∴nCpdtA=nCvdTB
∴dTB=(CvCp)dTA
=λ(dTA)[γ=1.4(diatomic)]
(dTA=30K)
=(1.4)(30K)
∴dTB=42K