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Question

Chemistry Question on packing efficiency

Total volume of atoms present in a face centred cubic unit cell of a metal is ( r=r= atomic radius)

A

203πr3\frac{20}{3}\pi {{r}^{3}}

B

243πr3\frac{24}{3}\pi {{r}^{3}}

C

123πr3\frac{12}{3}\pi {{r}^{3}}

D

163πr3\frac{16}{3}\pi {{r}^{3}}

Answer

163πr3\frac{16}{3}\pi {{r}^{3}}

Explanation

Solution

Volume of an atom =43πr3=\frac{4}{3} \pi r^{3} In fcc, number of atoms per unit cell =4=4 \therefore Volume of total atoms =4×43πr3=4 \times \frac{4}{3} \pi r^{3} =163π3=\frac{16}{3} \pi^{3}