Solveeit Logo

Question

Chemistry Question on The solid state

Total volume of atoms present in a face centred cubic unit cell of a metal is (rr is atomic radius)

A

163πr3\frac{16}{3} \pi r^3

B

203πr3\frac{20}{3} \pi r^3

C

243πr3\frac{24}{3} \pi r^3

D

123πr3\frac{12}{3} \pi r^3

Answer

163πr3\frac{16}{3} \pi r^3

Explanation

Solution

In fccfcc, no. of spheres in the unit cell
=8×18+6×12=4= 8 \times \frac{1}{8} + 6 \times \frac{1}{2} = 4
Volume of 4 spheres = 4×43πr3=163πr34 \times \frac{4}{3} \pi r^3 = \frac{16}{3} \pi r^3