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Question

Question: Total surface area of a cathode is 0.05 m<sup>2</sup> and 1 A current passes through it for 1 hour. ...

Total surface area of a cathode is 0.05 m2 and 1 A current passes through it for 1 hour. Thickness of nickel deposited on the cathode is (Given that density of nickel = 9 gm/cc and it’s ECE = 3.04 × 10–4gm/C)

A

2.4 m

B

2.4 cm

C

2.4 μm

D

None of these

Answer

2.4 μm

Explanation

Solution

Mass deposited = density × volume of the metal

m = ρ × A × x …… (i)

Hence from Faraday first law m = Zit ……(ii)

So from equation (i) and (ii) Zit = ρ × Axx=ZitρA=3.04×104×103×1×36×......9000×0.05=2.4×106m=2.4μmx = \frac{Zit}{\rho A} = \frac{3.04 \times 10^{- 4} \times 10^{- 3} \times 1 \times 36 \times ......}{9000 \times 0.05} = 2.4 \times 10^{- 6}m = 2.4\mu m