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Question

Chemistry Question on Surface Chemistry

TLC
In the given TLC, the distance of spot AA and BB are 5 cm and 7 cm, from the bottom of the TLC plate, respectively. The RfR_f value of BB is x×101x \times 10^{-1} times more than AA. The value of xx is _________ .

Answer

The distance of the solvent front from the bottom of the TLC plate is:
Solvent front: 10 cm.
The RfR_f value is given by:
Rf=Distance traveled by the spotDistance traveled by the solvent frontR_f = \frac{\text{Distance traveled by the spot}}{\text{Distance traveled by the solvent front}}
For spot A:
Rf(A)=510=0.5R_f(A) = \frac{5}{10} = 0.5
For spot B:
Rf(B)=710=0.7R_f(B) = \frac{7}{10} = 0.7
According to the question:
Rf(B)=x×101×Rf(A)R_f(B) = x \times 10^{-1} \times R_f(A)
Substitute the known values:
0.7=x×101×0.50.7 = x \times 10^{-1} \times 0.5
Simplify:
x=0.70.5×101=0.70.05=15x = \frac{0.7}{0.5 \times 10^{-1}} = \frac{0.7}{0.05} = 15
Final Answer: x=15x = 15.

Explanation

Solution

The distance of the solvent front from the bottom of the TLC plate is:
Solvent front: 10 cm.
The RfR_f value is given by:
Rf=Distance traveled by the spotDistance traveled by the solvent frontR_f = \frac{\text{Distance traveled by the spot}}{\text{Distance traveled by the solvent front}}
For spot A:
Rf(A)=510=0.5R_f(A) = \frac{5}{10} = 0.5
For spot B:
Rf(B)=710=0.7R_f(B) = \frac{7}{10} = 0.7
According to the question:
Rf(B)=x×101×Rf(A)R_f(B) = x \times 10^{-1} \times R_f(A)
Substitute the known values:
0.7=x×101×0.50.7 = x \times 10^{-1} \times 0.5
Simplify:
x=0.70.5×101=0.70.05=15x = \frac{0.7}{0.5 \times 10^{-1}} = \frac{0.7}{0.05} = 15
Final Answer: x=15x = 15.